Composite Modifiers to Improve the Rheological Properties of Asphalt Binders
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 6
Abstract
For the last 20 years, researchers have been looking for ways to modify asphalt binders to improve their rheological and thermophysical properties. The application of composite modifiers to enhance the rheological properties of asphalt binders offers a potential remedy for this significant issue. Because of this, this study looked at how composite modifiers affected the plain binder’s rheological characteristics. This study examined the rheological properties of unmodified and modified binders using a variety of formulations to blend modifiers including linear styrene-butadiene-styrene (SBS), radial SBS, Elvaloy, and polyphosphoric acid (PPA). The effect of PPA on the properties of polymer-added binders at low temperatures was investigated. Additionally, modifications using PPA aim to reduce the polymer content. Based on traditional performance classification (PG) and multiple stress creep recovery (MSCR) systems, original, rolling thin film oven–aged, and pressure aging vessel–aged binders were divided into three groups using a dynamic shear rheometer (DSR). The performance of binders at low temperatures was also assessed using the bending beam rheometer (BBR). All of the study’s additions were discovered to have enhanced the neat binder’s high-temperature capabilities. The elastic property of the neat binder was increased by the addition of Elvaloy and PPA. Results showed that, although the PPA modifier reduced the hardness of neat asphalt binder at low temperatures, other additives did not show significant effects on the hardness of the binder. The MSCR procedure was successfully utilized to grade all of the binders, but it appears that some binders and conditions do not fit the MSCR protocol’s “percent difference” criterion. According to the study’s findings, SBS can be replaced by 611 elastomer to enhance the performance of binders at high and moderate temperatures.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
Author contributions: Beyza Furtana YALÇIN: Methodology, Writing–original draft, Investigation, Data curation, Result presentation, Resources. Esma BAKIR: Data curation, Result presentation, Resources. Erkut YALÇIN: Investigation; Methodology, Roles/Writing–original draft; Writing–review and editing. Mehmet YILMAZ: Writing–review and editing, Supervision, Result presentation, Validation, Conceptualization.
References
AASHTO. 2013a. Standard pratice for determining rut depth pavements, American association of state highway and transportation officials. Washington, DC: AASHTO.
AASHTO. 2013b. Standard pratice for quantifying crack in asphalt pavement surface, American association of state highway and transportation officials. Washington, DC: AASHTO.
AASHTO. 2022a. Standard method of test for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). AASHTO T 313. Washington, DC: AASHTO.
AASHTO. 2022b. Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR). AASHTO T 315. Washington, DC: AASHTO.
AASHTO. 2023a. Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR). AASHTO T 350. Washington, DC: AASHTO.
AASHTO. 2023b. Standard specification for performance–graded asphalt binder, American association of state highway and transportation officials. AASHTO M 320. Washington, DC: AASHTO.
AASHTO. 2023c. Standard specification for performance–graded asphalt binder using multiple stress creep recovery (MSCR) test. AASHTO T 332. Washington, DC: AASHTO.
Airey, G. D. 2002. “Rheological evaluation of ethylene vinyl acetate polymer modified bitumens.” Constr. Build. Mater. 16 (8): 473–487. https://doi.org/10.1016/S0950-0618(02)00103-4.
ASTM. 2015. Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer. ASTM D 4402. West Conshohocken, PA: ASTM.
ASTM. 2018. Standard test method for density of semi-solid asphalt binder (pycnometer method). ASTM D70-18a. West Conshohocken, PA: ASTM.
Baldino, N., D. Gabriele, F. R. Lupi, C. O. Rossi, P. Caputo, and T. Falvo. 2013. “Rheological effects on bitumen of polyphosphoric acid (PPA) addition.” Constr. Build. Mater. 40 (Mar): 397–404. https://doi.org/10.1016/j.conbuildmat.2012.11.001.
Becker, M. Y., A. J. Muller, and Y. Rodriguez. 2003. “Use of rheological compatibility criteria to study SBS modified asphalts.” J. Appl. Polym. Sci. 90 (7): 1772–1782. https://doi.org/10.1002/app.12764.
Behnood, A., and M. M. Gharehveran. 2019. “Morphology, rheology, and physical properties of polymer-modified asphalt binders.” Eur. Polym. J. 112 (Mar): 766–791. https://doi.org/10.1016/j.eurpolymj.2018.10.049.
Behnood, A., and J. Olek. 2017a. “Rheological properties of asphalt binders modified with styrene-butadiene-styrene (SBS), ground tire rubber (GTR), or polyphosphoric acid (PPA).” Constr. Build. Mater. 151 (Oct): 464–478. https://doi.org/10.1016/j.conbuildmat.2017.06.115.
Behnood, A., and J. Olek. 2017b. “Stress-dependent behavior and rutting resistance of modified asphalt binders: An MSCR approach.” Constr. Build. Mater. 157 (Dec): 635–646. https://doi.org/10.1016/j.conbuildmat.2017.09.138.
Bektaş Atıcı, İ., E. Yalcin, and M. Yılmaz. 2023. “Investigation of the rheological properties of low-density polyethylene (LDPE) modified bitumens using two plastic wastes.” Sigma J. Eng. Nat. Sci. 41 (1): 26–34. https://doi.org/10.14744/sigma.2023.00003.
BSI (British Standards Institution). 2015a. Bitumen and bituminous binders—Determination of hardening resistance under the influence of heat and air, Türkiye. TS EN 12607-1. London: BSI.
BSI (British Standards Institution). 2015b. Bitumen and bituminous binders—Determination of needle penetration. BS EN 1426. London: BSI.
BSI (British Standards Institution). 2015c. Bitumen and bituminous binders—Determination of the softening point. BS EN 1427. London: BSI.
BSI (British Standards Institution). 2015d. Bitumen and bituminous binders—Determination of solubility, Türkiye. TS EN 12592. London: BSI.
Cao, W., S. Liu, and X. Li. 2017. “Laboratory evaluation of the effect of composite modifier on the performance of asphalt concrete mixture.” Constr. Build. Mater. 155 (Nov): 363–370. https://doi.org/10.1016/j.conbuildmat.2017.08.038.
Dong, Z., C. Yang, H. Luan, T. Zhou, and P. Wang. 2019a. “Chemical characteristics of bio-asphalt and its rheological properties after CR/SBS composite modification.” Constr. Build. Mater. 200 (Mar): 46–54. https://doi.org/10.1016/j.conbuildmat.2018.12.092.
Dong, Z.-J., T. Zhou, H. Luan, R. C. Williams, P. Wang, and Z. Leng. 2019b. “Composite modification mechanism of blended bio-asphalt combining styrene-butadiene-styrene with crumb rubber: A sustainable and environmental-friendly solution for wastes.” J. Cleaner Prod. 214 (Mar): 593–605. https://doi.org/10.1016/j.jclepro.2019.01.004.
Faxina, A. L., T. F. Pamplona, F. P. Sobreiro, and G. T. P. Fabbri. 2015. “Effect of polyphosphoric acid on high-temperature properties of bitumens from different crude sources.” In Proc., Bituminous Mixtures and Pavements VI, 127–132. Boca Raton, FL: CRC Press.
Feng, X., Z. Ning, Y. Mao, Y. Yang, and X. Yang. 2023. “Mechanical damage characteristics of CR/PPA composite modified asphalt pavement under multi-factor coupling effect in the seasonally frozen region.” Case Stud. Constr. Mater. 19 (Dec): e02296. https://doi.org/10.1016/j.cscm.2023.e02296.
Garilli, E., F. Autelitano, and F. Giuliani. 2019. “Use of bending beam rheometer test for rheological analysis of asphalt emulsion-cement mastics in cold in-place recycling.” Constr. Build. Mater. 222 (Oct): 484–492. https://doi.org/10.1016/j.conbuildmat.2019.06.141.
Han, M., J. Li, Y. Muhammad, Y. Yin, J. Yang, S. Yang, and S. Duan. 2018. “Studies on the secondary modification of SBS modified asphalt by the application of octadecyl amine grafted graphene nanoplatelets as modifier.” Diamond Relat. Mater. 89 (Oct): 140–150. https://doi.org/10.1016/j.diamond.2018.08.011.
Han, Y., B. Cui, J. Tian, J. Ding, F. Ni, and D. Lu. 2022. “Evaluating the effects of styrene-butadiene rubber (SBR) and polyphosphoric acid (PPA) on asphalt adhesion performance.” Constr. Build. Mater. 321 (Feb): 126028. https://doi.org/10.1016/j.conbuildmat.2021.126028.
Hassanpour-Kasanagh, S., P. Ahmedzade, A. M. Fainleib, and A. Behnood. 2020. “Rheological properties of asphalt binders modified with recycled materials: A comparison with styrene-butadiene-styrene (SBS).” Constr. Build. Mater. 230 (Jan): 117047. https://doi.org/10.1016/j.conbuildmat.2019.117047.
Jasso, M., R. Hampl, O. Vacin, D. Bakos, J. Stastna, and L. Zanzotto. 2015. “Rheology of conventional asphalt modified with SBS, Elvaloy and polyphosphoric acid.” Fuel Process. Technol. 140 (Dec): 172–179. https://doi.org/10.1016/j.fuproc.2015.09.002.
Ju, Z., D. Ge, Z. Wu, Y. Xue, S. Lv, Y. Li, and X. Fan. 2022. “The performance evaluation of high content bio-asphalt modified with polyphosphoric acid.” Constr. Build. Mater. 361 (Dec): 129593. https://doi.org/10.1016/j.conbuildmat.2022.129593.
Kok, B. V., B. F. Yalcin, M. Yilmaz, and E. Yalcin. 2022a. “Effects of using styrene-isoprene-styrene and crumb rubber on rutting potential and aging properties of bitumen.” Environ. Eng. Manage. J. 21 (6): 1025–1035. https://doi.org/10.30638/eemj.2022.092.
Kok, B. V., B. F. Yalcin, M. Yilmaz, and E. Yalcin. 2022b. “Performance evaluation of bitumen modified with styrene-isoprene-styrene and crumb rubber compound.” Constr. Build. Mater. 344 (Aug): 128304. https://doi.org/10.1016/j.conbuildmat.2022.128304.
Lesueur, D. 2009. “The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification.” Adv. Colloid Interface Sci. 145 (1–2): 42–82. https://doi.org/10.1016/j.cis.2008.08.011.
Li, J., F. Xiao, and S. N. Amirkhanian. 2020. “Rheological and chemical characterization of plasma-treated rubberized asphalt using customized extraction method.” Fuel 264 (Mar): 116819. https://doi.org/10.1016/j.fuel.2019.116819.
Liang, P., M. Liang, W. Fan, Y. Zhang, C. Qian, and S. Ren. 2017. “Improving thermo-rheological behavior and compatibility of SBR modified asphalt by addition of polyphosphoric acid (PPA).” Constr. Build. Mater. 139 (Mar): 183–192. https://doi.org/10.1016/j.conbuildmat.2017.02.065.
Navarro, F. J., P. Partal, F. Martínez-Boza, C. Gallegos, J. C. M. Bordado, and A. C. Diogo. 2006. “Rheology and microstructure of MDI–PEG reactive prepolymer-modified bitumen.” Mech. Time-Depend. Mater. 10 (4): 347–359. https://doi.org/10.1007/s11043-007-9029-2.
Office of Pavement Technology. 2012. “The use and performance of asphalt binder modified with polyphosphoric acid (PPA).” Accessed December 29, 2023. https://www.fhwa.dot.gov/pavement/asphalt/pubs/hif12030.pdf.
Qian, C., W. Fan, M. Liang, Y. He, S. Ren, X. Lv, G. Nan, and H. Luo. 2018. “Rheological properties, storage stability and morphology of CR/SBS composite modified asphalt by high-cured method.” Constr. Build. Mater. 193 (Dec): 312–322. https://doi.org/10.1016/j.conbuildmat.2018.10.158.
Qian, C., W. Fan, F. Ren, X. Lv, and B. Xing. 2019. “Influence of polyphosphoric acid (PPA) on properties of crumb rubber (CR) modified asphalt.” Constr. Build. Mater. 227 (Dec): 117094. https://doi.org/10.1016/j.conbuildmat.2019.117094.
Yalcin, E., and A. Demirbag. 2022. “Effects of modified binders obtained from different polymers on conventional and rheological properties.” Constr. Build. Mater. 357 (Nov): 129366. https://doi.org/10.1016/j.conbuildmat.2022.129366.
Yang, X., G. Liu, H. Rong, Y. Meng, C. Peng, M. Pan, Z. Ning, and G. Wang. 2022. “Investigation on mechanism and rheological properties of bio-asphalt/PPA/SBS modified asphalt.” Constr. Build. Mater. 347 (Sep): 128599. https://doi.org/10.1016/j.conbuildmat.2022.128599.
Yildirim, Y. 2007. “Polymer modified asphalt binders.” Constr. Build. Mater. 21 (1): 66–72. https://doi.org/10.1016/j.conbuildmat.2005.07.007.
Zhang, H., and M. Gong. 2018. “Study on durability of composite-modified asphalt mixture based on inherent and improved performance.” Constr. Build. Mater. 179 (Aug): 539–552. https://doi.org/10.1016/j.conbuildmat.2018.05.260.
Information & Authors
Information
Published In
Copyright
© 2024 American Society of Civil Engineers.
History
Received: Aug 18, 2023
Accepted: Nov 6, 2023
Published online: Mar 18, 2024
Published in print: Jun 1, 2024
Discussion open until: Aug 18, 2024
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.
Cited by
- Saeid Hesami, Mohammad Mahzari, Saeid Sobhi, Mohammad Ali Bay, Investigating the rheological properties and microstructural analysis of Nano-expanded Perlite modified asphalt binder, Case Studies in Construction Materials, 10.1016/j.cscm.2025.e04208, 22, (e04208), (2025).
- Mahyar Arabani, Amir Amiri, Mohammad Hossein Hassanjani, Utilizing olive pomace oil and the extrusion of SBS and PVC to enhance the physical and rheological characteristics of asphalt binder, Case Studies in Construction Materials, 10.1016/j.cscm.2024.e04097, 21, (e04097), (2024).
- Zhisheng Liu, Xiaolong Sun, Hualong Xu, Yuanyu Lu, Zipeng Su, Yuanchang Ye, Guoxuan Huang, Anti-Aging Performance and Action Mechanism of Asphalt Modified by Composite Modification, Applied Sciences, 10.3390/app142210250, 14, 22, (10250), (2024).
- Ao Lu, Ming Xiong, Chen Chen, Liangjiang Li, Haibei Tan, Xiong Xu, Physical-Rheological Properties and Performances of Rejuvenated (Styrene-Butadiene-Styrene) Asphalt with Polymerized-MDI and Aromatic Oil, Fluid Dynamics & Materials Processing, 10.32604/fdmp.2024.051010, 20, 7, (1633-1646), (2024).